2,6-Naphthalenedicarboxylic Acid CAS 1141-38-4 - High Quality from China Suppliers & Factory
What is 2,6-Naphthalenedicarboxylic Acid (2,6-NDA)?
2,6-Naphthalenedicarboxylic Acid (CAS No. 1141-38-4), commonly referred to as 2,6-NDA, is a pivotal aromatic dicarboxylic acid with the chemical formula C₁₂H₈O₄ and a molecular weight of 216.19 g/mol. It presents as a white, crystalline solid with an exceptionally high melting point exceeding 300°C, renowned for its remarkable chemical stability and structural rigidity. This compound is a fundamental building block in advanced polymer chemistry, serving as a critical monomer for synthesizing high-performance materials that outperform conventional petrochemical-based polymers.
The core functionality of 2,6-NDA stems from its unique molecular structure—a rigid naphthalene ring functionalized with two carboxyl groups (-COOH) at the 2 and 6 positions. This symmetrical, linear structure imparts exceptional rigidity and thermal stability to the polymers derived from it.
Its primary chemical reactivity lies in esterification, where it readily reacts with diols to form robust polyester chains. Unlike terephthalic acid (used for PET), the fused aromatic rings of 2,6-NDA confer superior mechanical strength, enhanced heat resistance, excellent gas barrier properties, and outstanding UV resistance to the resulting materials. These attributes make 2,6-NDA indispensable for manufacturing products that demand extreme durability and performance under harsh conditions.
Application
The most prominent application of 2,6-NDA is in the production of Polyethylene Naphthalate (PEN), a high-performance polyester. PEN, synthesized via the polycondensation of 2,6-NDA (or its dimethyl ester, NDC) with ethylene glycol, exhibits vastly superior properties compared to PET. It boasts a higher glass transition temperature (Tg), greater tensile strength, and significantly improved barrier capabilities against oxygen, carbon dioxide, and water vapor. Consequently, PEN is extensively used in high-end food packaging for extended shelf-life products, high-strength industrial fibers, tire cords, and specialized films for flexible printed circuits, magnetic recording tapes, and electrical insulation. It is also the material of choice for F-class electrical insulation, capable of withstanding continuous high-temperature operating environments.
Beyond PEN, 2,6-NDA is a key monomer for producing other advanced polymers. It is used to synthesize Polybutylene Naphthalate (PBN), which offers excellent melt processability combined with high thermal stability, ideal for engineering plastic components. Furthermore, it is a critical component in manufacturing Liquid Crystal Polymers (LCPs), which exhibit exceptional flowability, dimensional stability, and flame resistance. LCPs are vital in the electronics industry for producing high-density connectors, sockets, and surface-mount devices.
Additionally, 2,6-NDA serves as a versatile organic building block and ligand in the synthesis of Metal-Organic Frameworks (MOFs), where its rigid structure helps form porous, crystalline materials used in gas storage, separation, catalysis, and even as potential drug delivery carriers. It also finds utility as an intermediate in pharmaceuticals, dyestuffs, and various specialty fine chemicals.
In summary, 2,6-Naphthalenedicarboxylic Acid is a cornerstone chemical for the advanced materials sector. Its unique ability to form ultra-stable, high-performance polymers has solidified its role as an indispensable raw material, driving innovation in packaging, electronics, automotive, aerospace, and industrial manufacturing industries.
Details
Frequently Asked Questions (FAQ)
Q
What is the CAS number and chemical formula of 2,6-NDA?
2,6-Naphthalenedicarboxylic Acid (2,6-NDA) has the CAS registry number 1141-38-4 and the chemical formula C₁₂H₈O₄.
Q
Why is 2,6-NDA preferred over terephthalic acid for high-performance applications?
Unlike terephthalic acid used for standard PET, the fused aromatic rings of 2,6-NDA provide the resulting polymers with superior mechanical strength, higher thermal stability, enhanced gas barrier properties, and outstanding UV resistance.
Q
What is Polyethylene Naphthalate (PEN) and how is it used?
PEN is a high-performance polyester synthesized from 2,6-NDA and ethylene glycol. It is widely used in high-end food packaging, high-strength industrial fibers, tire cords, flexible printed circuits, and F-class electrical insulation due to its superior barrier and thermal properties.
Q
Can 2,6-NDA be used to make polymers other than PEN?
Yes, it is also a key monomer for producing Polybutylene Naphthalate (PBN) for engineering plastics and Liquid Crystal Polymers (LCPs) used for high-density connectors and electronic devices.
Q
What role does 2,6-NDA play in Metal-Organic Frameworks (MOFs)?
2,6-NDA acts as a rigid ligand in synthesizing MOFs. Its stable structure helps form porous crystalline materials used for gas storage, gas separation, catalysis, and targeted drug delivery systems.





